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Simultaneously Enhancing Efficiency and Stability of Perovskite Solar Cells Through Crystal Cross-Linking Using Fluorophenylboronic Acid.

Mingguang LiHuan GaoLongsheng YuSenlin TangYing PengChao ZhengLigang XuYe TaoRunfeng ChenWei Huang
Published in: Small (Weinheim an der Bergstrasse, Germany) (2021)
Organic-inorganic metal halide perovskites are regarded as one of the most promising candidates in the photovoltaic field, but simultaneous realization of high efficiency and long-term stability is still challenging. Here, a one-step solution-processing strategy is demonstrated for preparing efficient and stable inverted methylammonium lead iodide (MAPbI3 ) perovskite solar cells (PSCs) by incorporating a series of organic molecule dopants of fluorophenylboronic acids (F-PBAs) into perovskite films. Studies have shown that the F-PBA dopant acts as a cross-linker between neighboring perovskite grains through hydrogen bonds and coordination bonds between F-PBA and perovskite structures, yielding high-quality perovskite crystalline films with both improved crystallinity and reduced defect densities. Benefiting from the repaired grain boundaries of MAPbI3 with the organic cross-linker, the inverted PSCs exhibit a remarkably enhanced performance from 16.4% to approximately 20%. Meanwhile, the F-PBA doped devices exhibit enhanced moisture/thermal/light stability, and specially retain 80% of their initial power conversion efficiencies after more than two weeks under AM 1.5G one-sun illumination. This work highlights the impressive advantages of the perovskite crystal cross-linking strategy using organic molecules with strong intermolecular interactions, providing an efficient route to prepare high-performance and stable planar PSCs.
Keyphrases
  • perovskite solar cells
  • high efficiency
  • room temperature
  • solar cells
  • water soluble
  • ionic liquid
  • high resolution
  • solid state
  • mass spectrometry
  • case control