Enantioselective Syntheses of Homopropargylic Alcohols via Asymmetric Allenylboration.
Mengzhou WangShahriar KhanEvangelos MiliordosMing ChenPublished in: Organic letters (2018)
A chiral phosphoric acid catalyzed allenylboration reaction is reported. Homopropargyl alcohols with an internal alkyne unit were obtained in good yields with high enantioselectivities under the developed conditions.