Nickel-Catalyzed Stereoselective Diarylation of Alkenylarenes.

Pin GaoLiang-An ChenM Kevin Brown

Published in: Journal of the American Chemical Society (2018)

A three-component coupling of aryl bromides, arylboron reagents, and alkenylarenes is presented. The method tolerates a variety of substitution patterns on all of the components. In particular, 1,2-disubstituted alkenylarenes are suitable and undergo highly diastereoselective diarylation.

Keyphrases

room temperature
reduced graphene oxide
ionic liquid
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electron transfer