Hydrogen bonds-triggered differential extraction efficiencies for bifenthrin by three polymeric ionic liquids with varying anions based on FT-IR spectroscopy.

Herein, we fabricated three imidazolium-based polymeric ionic liquids (PILs) with different anions (P[VEIM]BF 4 , P[VEIM]PF 6 and P[VEIM]Br), and analyzed their differential extraction efficiencies for bifenthrin through H-bonding induced effects. Three PILs all presented an irregular block structure with rough surface and lower specific-surface area (SSA, 11.2-18.7 m 2 g -1 ) than carbon-based nanomaterials. They formed hydrogen bonds with free-water molecules in the lattice of PILs, including C 2,4,5 -H⋯O-H, Br⋯H-O-H⋯Br, O-H⋯Br, C 2,4,5 -H⋯F-P, P-F⋯H-O-H⋯F-P, C 2,4,5 -H⋯F-B and B-F⋯H-O-H⋯F-B. After extraction, the O-H stretching-vibration peak was prominently intensified, whereas the C-H bond varied slightly concomitant with reduced B-F and P-F vibration. Theoretically, the C-H vibration should become more intense in the C 4,5 -H⋯H 2 O and C 2 -H⋯H 2 O bonds after extraction in contrast to before extraction. These contrary spectral changes demonstrated that the hydrogen bonds between cations in the PILs and free-water molecules were broken after extraction, yielding the H-bonding occurrence between bifenthrin and H-O-H in the lattice. As a time indicator for the free-water binding and releasing process, the highest slope for the plot of I t / I 0 against time implied that the shortest time was required for P[VEIM]PF 6 to reach an adsorption equilibrium. Overall, the strong hydrophobicity, small SSA and electrostatic-repulsion force for P[VEIM]PF 6 are all not conducive to its efficient adsorption. Beyond our anticipation, P[VEIM]PF 6 provided the highest extraction recovery for bifenthrin up to 92.4% among three PILs. Therefore, these data lead us to posit that the above high efficiency results from the strongest H-bonding effect between P[VEIM]PF 6 and bifenthrin. These findings promote our deep understanding of PILs-triggered differential efficiency through a H-bonding induced effect.