Sorption of Cu(II), Zn(II) and Pb(II) Ions in an Aqueous Solution on the PVC-Acetylacetone Composites.

The possibility of removing Cu(II), Zn(II) and Pb(II) ions by sorption on new PVC-based composite materials with different contents of acetylacetone (acac) and porophor was investigated. Composites were characterized using a scanning electron microscope and by infrared spectral analysis (FTIR). Sorption tests were conducted at 20 °C. It has been shown that the equilibrium is established in about 4 h. The reduction in ion concentration in the solution depended on the content of both acac and porophor in the composite. The maximal reduction in ion concentration ranged from 8% to 91%, 10⁻85% and 6⁻50% for Cu(II), Zn(II) and Pb(II) ions, respectively, depending on the composite composition. The best results were obtained for the composite containing 30% w/w of acac and 10% of porophor. For this composite, the sorption capacity after 4 h sorption for Zn(II), Cu(II) and Pb(II) ions was 26.65, 25.40, and 49.68 mg/g, respectively. Kinetic data were best fitted with a pseudo⁻second-order equation.