Facile access to high-efficiency degradation of tetracycline hydrochloride with structural optimization of TiN.

As a broad-spectrum antibiotic, tetracycline has become a potential ecological hazard. Herein, titanium nitride (TiN), with an advantageous structure, was synthesized by simple heating rate regulation and constructed for tetracycline hydrochloride (TC-HCl) degradation under light irradiation. All the samples were characterized by X-ray diffraction (XRD), N 2 -adsorption/desorption isotherm, ultraviolet-visible diffuse reflectometry (DRS), scanning electron microscopy (SEM), and electrochemical impedance spectroscopy (EIS). The results showed that the as-prepared TiN-x catalysts exhibited obviously enhanced photocatalytic property toward TC-HCl degradation compared with the commercial pure phase TiN (p-TiN). According to the results of photocatalytic degradation, TiN synthesized at 6 °C/min heating rate had the best removal rate of TC-HCl (90%) after dark reaction for 10 min and photo-degradation for 90 min. In addition, the trapping experiments have demonstrated that the photogenerated holes (h + ) and superoxide radical ([Formula: see text]) are the main oxidation products of the present system. Strikingly, the reuse experiments showed high stability of TiN.