Metal-Based Diversity for Crystalline Metal-Fullerene Frameworks.
Andreas KraftChantal RogerDavid SchmidtJohannes StanglKlaus Müller-BuschbaumFlorian BeuerlePublished in: Chemistry (Weinheim an der Bergstrasse, Germany) (2017)
Four different three-dimensional metal-fullerene frameworks were synthesized through polymerization of two C60 -derived dodecaacids with varying alkyl spacers in the presence of Ca2+ , Cu2+ or Cd2+ ions. Structural analysis of the frameworks was performed by single-crystal X-ray diffraction and porosity of the materials was investigated by sorption measurements.