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A {Cu 6 }-added polyoxometalate cluster-organic framework: synthesis, structure and application as a solid support for enzyme immobilization.

Zhao-Min SuYongchun WangZhikun XuWenhui ShangZhiyu JiaGuo-Yu Yang
Published in: Dalton transactions (Cambridge, England : 2003) (2023)
A new two-dimensional {Cu6}-added polyoxometalate cluster-organic framework (Cu-POMCOF) was prepared by a hydrothermal method from lacunary polyoxoanions and was applied as a solid support for immobilizing MP-11 and Cyt c. The biocomposite complex exhibits higher stability and catalytic activity than the original free enzyme.
Keyphrases
  • metal organic framework
  • aqueous solution
  • heavy metals
  • anaerobic digestion
  • municipal solid waste