Post-functionalization of a photoactive hybrid polyoxotungstate.

Jamie M CameronSatomi FujimotoRong-Jia Wei Graham N Newton H Hiroki Oshio

Published in: Dalton transactions (Cambridge, England : 2003) (2018)

A new post-functionalization strategy for hybrid polyoxometalate (POM) clusters is presented, whereby the electronic properties and visible-light driven oxidative reactivity of the POM core can be altered by controlled addition of transition metal ions. The structure of three new metal-functionalised derivatives of a phosphonate hybrid-POM are discussed, alongside a comparison of their electrochemical, photo-chemical and photo-oxidative properties.

Keyphrases

visible light
transition metal
gold nanoparticles
electron transfer
quantum dots
mass spectrometry