Reversible Sn-Sn Triple Bond Dissociation in a Distannyne: Support for Charge-Shift Bonding Character.

Ting Yi Lai Lizhi Tao R David Britt Philip P Power

Published in: Journal of the American Chemical Society (2019)

The tin-tin triple bond in the distannyne AriPr4SnSnAriPr4, AriPr4 = C6H3-2,6(C6H3-2,6-iPr2)2, undergoes reversible cleavage in deuterated toluene to afford two :SṅAriPr4 radicals in solution as shown by 1H nuclear magnetic resonance and electron paramagnetic resonance spectroscopy. Variable temperature data afforded an enthalpy of dissociation of ΔHdiss = 17.2 ± 1.7 kcal mol-1 via van't Hoff analysis.

Keyphrases

electron transfer
magnetic resonance
electronic health record
high resolution
solar cells
oxide nanoparticles
energy transfer
solid state
dna binding
magnetic resonance imaging
perovskite solar cells
computed tomography
deep learning
artificial intelligence