Ethylene glycol nanofluids dispersed with monolayer graphene oxide nanosheet for high-performance subzero cold thermal energy storage.

Ethylene glycol (EG) nanofluids have been intensively explored as one of the most promising solid-liquid phase change materials for subzero cold thermal energy storage (CTES). However, the prepared nanofluids usually suffer from a large supercooling degree, a long freezing period, reduced storage capacity and poor dispersion stability. Herein, we overcome these issues by developing stable EG nanofluids that are uniformly dispersed with low concentrations of monolayer ethanol-wetted graphene oxide nanosheets. The homogeneously dispersed monolayer sheet not only improves the thermal conductivity of the nanofluids (12.1%) but also provides the heterogeneous nucleation sites to trigger the crystal formation, thereby shortening the freezing time and reducing the supercooling degree. Compared with the base fluid, the nanofluids have reduced the supercooling degree by 87.2%, shortened the freezing time by 78.2% and maintained 98.5% of the latent heat. Moreover, the EG nanofluids have retained their initial stable homogeneous dispersion after repeated freezing/melting for 50 cycles, which ensures consistent CTES behavior during long-period operations. The facile preparation process, low loading requirement and consistent superior thermophysical properties would make the EG nanofluids loaded with monolayer graphene oxide sheets promising coolants for high-performance phase change-based CTES.