Login / Signup

Lattice Strain and Mott-Schottky Effect of the Charge-Asymmetry Pd 1 Fe Single-Atom Alloy Catalyst for Semi-Hydrogenation of Alkynes with High Efficiency.

Zhiyi SunChen LiJie LinTianqi GuoShaojia SongYaning HuZedong ZhangWensheng YanYu WangZihao WeiFang ZhangKun ZhengDingsheng S WangZhenxing LiShuo WangWenxing Chen
Published in: ACS nano (2024)
The ideal interface design between the metal and substrate is crucial in determining the overall performance of the alkyne semihydrogenation reaction. Single-atom alloys (SAAs) with isolated dispersed active centers are ideal media for the study of reaction effects. Herein, a charge-asymmetry "armor" SAA (named Pd 1 Fe SAA@PC), which consists of a Pd 1 Fe alloy core and a semiconducting P-doped C (PC) shell, is rationally designed as an ideal catalyst for the selective hydrogenation of alkynes with high efficiency. Multiple spectroscopic analyses and density functional theory calculations have demonstrated that Pd 1 Fe SAA@PC is dual-regulated by lattice tensile and Schottky effects, which govern the selectivity and activity of hydrogenation, respectively. (1) The PC shell layer applied an external traction force causing a 1.2% tensile strain inside the Pd 1 Fe alloy to increase the reaction selectivity. (2) P doping into the C-shell layer realized a transition from a p-type semiconductor to an n-type semiconductor, thereby forming a unique Schottky junction for advancing alkyne semihydrogenation activity. The dual regulation of lattice strain and the Schottky effect ensures the excellent performance of Pd 1 Fe SAA@PC in the semihydrogenation reaction of phenylethylene, achieving a conversion rate of 99.9% and a selectivity of 98.9% at 4 min. These well-defined interface modulation strategies offer a practical approach for the rational design and performance optimization of semihydrogenation catalysts.
Keyphrases
  • metal organic framework
  • high efficiency
  • density functional theory
  • visible light
  • molecular dynamics
  • room temperature
  • highly efficient
  • aqueous solution
  • ionic liquid
  • solar cells