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Luminescent PhotoCORMs: Enabling/Disabling CO Delivery upon Blue Light Irradiation.

Vitor C WeissGiliandro FariasAndré L AmorimFernando R XavierTiago P CamargoMayana B BregaldaMatti HaukkaEbbe NordlanderBernardo de SouzaRosely Aparecida Peralta
Published in: Inorganic chemistry (2020)
The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.
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