Synthesis and characterization of cylindrical electrode with sucrose binder as advanced electrode materials for copper 3D-electro-oxidation.

This study produced a biomass-based cylindrical electrode containing sucrose (an organic binder). The Cu 2+ removal performance of the synthesized sucrose-bonded cylindrical electrode was evaluated in a 3-phase 3-dimensional electro-oxidation reactor (3D-EO) and the classical electro-oxidation method (2D-EO). Sodium Dodecyl Sulfate (SDs) was grafted onto activated carbon and used as microelectrode in 3D-EO reactors. SDs grafting resulted in a 57% reduction in the micropores of activated carbon. Therefore, the surface area of carbon after grafting decreased from 1328 m 2 /g to 580 m 2 /g. The sucrose-bonded cylindrical electrode has a rich carbon structure and consists of 84.04 wt% C, 12.10 wt% O and 3.20 wt%Si. According to CV measurement, the sucrose-bonded cylindrical electrode gives a surface reaction against Cu 2+ at voltages lower than -0.62 V. Increasing the potential difference from 1V to 3V in 2D-EO and 3D-EO processes led to the removal of Cu 2+ from the solution. The 3D-EO reactor achieved a removal rate of 87.12% at 3V. The 100 ppm solution was treated with a 3D-EO reactor containing 6 g/L of PC/SDs400Ws for 60 min, successfully removing 91.22% of Cu 2+ .