Electrocatalytic Microdevice Array Based on Wafer-Scale Conductive Metal-Organic Framework Thin Film for Massive Hydrogen Production.

The synthesis of large-scale 2D conductive metal-organic framework films with tunable thickness is highly desirable but challenging. In this study, an Interface Confinement Self-Assembly Pulling (ICSP) method for in situ synthesis of 4-in. Ni-BHT film on the substrate surface is developed. By modulating the thickness of the confined space, the thickness of Ni-BHT films could be easily varied from 4 to 42 nm. To eliminate interference factors and evaluate the effect of film thickness on the catalytic performance of HER, an electrocatalytic microdevice based on the Ni-BHT film is designed. The effective catalytic thickness of the Ni-BHT film is found to be around 32 nm. Finally, to prepare the electrocatalytic microdevice array, over 100 000 microdevices on a 4-in. Ni-BHT film are integrated. The results show that the microdevice array has good stability and a high hydrogen production rate and could be used to produce large amounts of hydrogen. The wafer-scale 2D conductive metal-organic framework's fabrication greatly advances the practical application of microdevices for massive hydrogen production.