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Triplet dynamic nuclear polarization of nanocrystals dispersed in water at room temperature.

Koki NishimuraHironori KounoKenichiro TateishiTomohiro UesakaKeiko IdetaNobuo KimizukaNobuhiro Yanai
Published in: Physical chemistry chemical physics : PCCP (2019)
While dynamic nuclear polarization using photo-excited triplet electrons (triplet-DNP) can improve the sensitivity of nuclear magnetic resonance at room temperature, it has not been carried out in water. Here, we report the first example of triplet-DNP in water by downsizing the conventional bulk crystals to nanocrystals.
Keyphrases
  • room temperature
  • energy transfer
  • magnetic resonance
  • ionic liquid
  • quantum dots
  • magnetic resonance imaging
  • computed tomography
  • electron transfer