Achieving Ultra-Wideband NIR-II Emission in Cr 3+ -Doped Li(Sc,In)(Si,Ge)O 4 Phosphors Based on Host Composition Engineering.
Jiahui ZhangWenjing HuangJiaqi FanWeiying ZhouZhan-Chao WuChunyan ZhouLi-Ya ZhouQiang XiaoXinguo ZhangPublished in: Inorganic chemistry (2023)
Realizing ultra-wideband and tunable near-infrared (NIR) emission remains a great challenge in NIR phosphor development. The luminescence of most reported NIR phosphors exhibits a peak wavelength shorter than 1000 nm and the corresponding FWHM is <200 nm. Here, a series of Cr 3+ -activated Li(Sc,In)(Si,Ge)O 4 phosphors with ultra-wideband and tunable NIR-II emission are successfully developed based on the host composition engineering strategy. Significant spectral engineering in the NIR-II region is achieved with a peak wavelength changing from 1110 to 1253 nm. The olivine host structure could provide Cr 3+ activator a highly distorted octahedral site with very weak crystal field strength, which results in NIR-II ultra-wideband emission with FWHM > 300 nm. A detailed discussion on the relationship between structural variation, crystal field splitting, and NIR luminescence has been applied. As far as we know, it is the first report about Cr 3+ NIR luminescence engineering in such a long wavelength and wide range. The application of these NIR-II phosphors is demonstrated in intensity-based luminescent thermometry with a relative sensitivity of >2.0% K -1 in the physiological temperature range.