Atom-Precise Heteroatom Core-Tailoring of Nanoclusters for Enhanced Solar Hydrogen Generation.

While core-shell nanomaterials are highly desirable for realizing enhanced optical and catalytic properties, their synthesis with the atomic-level control is challenging. Here we present the synthesis and crystal structure of [Au 12 Ag 32 (SePh) 30 ] 4- , the first example of selenolated Au-Ag core-shell nanoclusters, comprising a gold icosahedron core trapped in a silver dodecahedron, which is protected by an Ag 12 (SePh) 30 shell. The gold core strongly modifies the overall electronic structure and induces synergistic effects, resulting in the high enhancements in the stability and near-infrared-II photoluminescence. The Au 12 Ag 32 and its homometal analogue Ag 44 , show strong interactions with oxygen vacancies of TiO 2 , facilitating the interfacial charge transfer for photocatalysis. Indeed, the Au 12 Ag 32 /TiO 2 exhibits remarkable solar H 2 production (6810 μmol g -1 h -1 ), which is ∼6.2 and ∼37.8 times higher than that of Ag 44 /TiO 2 and TiO 2 , respectively. Good stability and recyclability with minimal catalytic activity loss are additional features of Au 12 Ag 32 /TiO 2 . The experimental and computational results reveal that the Au 12 Ag 32 acts as an efficient cocatalyst by possessing a favorable electronic structure that aligns well with the TiO 2 bands for the enhanced separation of photoinduced charge carriers due to the relatively negatively charged Au 12 core. These atomistic insights will motivate uncovering of the structure-catalytic activity relationships of other nanoclusters. This article is protected by copyright. All rights reserved.