Using performance reference compounds to compare mass transfer calibration methodologies in passive samplers deployed in the water column.

Performance reference compounds (PRCs) are often added to passive samplers prior to field deployments to provide information about mass transfer kinetics between the sampled environment and the passive sampler. Their popularity has resulted in different methods of varying complexity to estimate mass transfer and better estimate freely dissolved concentrations (Cfree ) of targeted compounds. Three methods for describing a mass transfer model are commonly used: a first-order kinetic method, a nonlinear least squares fitting of sampling rate, and a diffusion method. Low-density polyethylene strips loaded with PRCs and of 4 different thicknesses were used as passive samplers to create an array of PRC results to assess the comparability and reproducibility of each of the methods. Samplers were deployed in the water column at 3 stations in New Bedford Harbor (MA, USA). Collected data allowed Cfree comparisons to be performed in 2 ways: 1) comparison of Cfree derived from one thickness using different methods, and 2) comparison of Cfree derived by the same method using different thicknesses of polyethylene. Overall, the nonlinear least squares and diffusion methods demonstrated the most precise results for all the PCBs measured and generated Cfree values that were often statistically indistinguishable. Relative standard deviations (RSDs) for total PCB measurements using the same thickness and varying model types ranged from 0.04 to 12% and increased with sampler thickness, and RSDs for estimates using the same method and varying thickness ranged from 8 to 18%. Environmental scientists and managers are encouraged to use these methods when estimating Cfree from passive sampling and PRC data. Environ Toxicol Chem 2018;37:2089-2097. Published 2018 Wiley Periodicals Inc. on behalf of SETAC. This article is a US government work and, as such, is in the public domain in the United States of America.