Inverse opals with reactive surface chemistry as sensors for aqueous pollutants.
Giulia MagnaboscoMaria OchsNatalie BonakdarLaura CzerwenkaAnnette Andrieu-BrunsenNicolas VogelPublished in: Chemical communications (Cambridge, England) (2024)
Inverse opal colorimetric sensors operating on wetting transitions usually rely on physical differences of the infiltrating liquid. Here, we exploit a reactive surface chemistry that changes wettability upon binding of an analyte. Upon binding of Fe 3+ to a Schiff base immobilized on the porous structure, the surface becomes more hydrophilic, triggering the infiltration of the structure and causing the structural color to disappear.