Synthesis, characterization, luminescence properties and deciphering the role of a terpyridyl-imidazole based ligand in the dissimilar luminescence sensitization of ternary lanthanide(III) tris-(β-diketonate) complexes.

We designed four ternary lanthanide tris-(β-diketonate) complexes of the form [Ln(tta) 3 (tpy-HImzphen)], where Ln = La III , Eu III , Sm III and Tb III ; tta = (2-theonyltrifluoroacetonate) and tpy-HImzphen = 2-(4-[2,2':6',2'']terpyridin-4'-yl-phenyl)-1 H -phenanthro[9,10- d ]imidazole. All the complexes have been thoroughly characterized by standard analytical tools and spectroscopic techniques including single crystal X-ray diffraction. In situ generation of the complexes was also monitored via absorption and emission spectroscopy upon incremental addition of the respective lanthanide precursor {Ln(tta) 3 (H 2 O) 2 } to the dichloromethane solution of the terpyridyl-imidazole ligand. The photophysical behaviors of all the complexes were thoroughly investigated via absorption and both steady-state and time-resolved emission spectroscopic techniques. The emission spectral measurements were carried out at both room temperature and 77 K to understand the deactivation dynamics of the excited states and elucidate the distinctive luminescence responses from the four lanthanide metal ions owing to the introduction of the terpyridyl-based ancillary ligand.