Login / Signup

Lead halide-templated crystallization of methylamine-free perovskite for efficient photovoltaic modules.

Tongle BuJing LiHengyi LiCongcong TianJie SuGuoqing TongLuis Katsuya OnoChao WangZhipeng LinNianyao ChaiXiao-Li ZhangJingjing ChangJianfeng LuJie ZhongWenchao HuangYabing QiYi-Bing ChengFuzhi Huang
Published in: Science (New York, N.Y.) (2021)
Upscaling efficient and stable perovskite layers is one of the most challenging issues in the commercialization of perovskite solar cells. Here, a lead halide-templated crystallization strategy is developed for printing formamidinium (FA)-cesium (Cs) lead triiodide perovskite films. High-quality large-area films are achieved through controlled nucleation and growth of a lead halide•N-methyl-2-pyrrolidone adduct that can react in situ with embedded FAI/CsI to directly form α-phase perovskite, sidestepping the phase transformation from δ-phase. A nonencapsulated device with 23% efficiency and excellent long-term thermal stability (at 85°C) in ambient air (~80% efficiency retention after 500 hours) is achieved with further addition of potassium hexafluorophosphate. The slot die-printed minimodules achieve champion efficiencies of 20.42% (certified efficiency 19.3%) and 19.54% with an active area of 17.1 and 65.0 square centimeters, respectively.
Keyphrases
  • solar cells
  • perovskite solar cells
  • room temperature
  • high efficiency
  • air pollution
  • ionic liquid
  • carbon nanotubes
  • network analysis