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Electric field-assisted NSR process for lean NO x reduction at low temperatures.

Ayaka ShigemotoYuki InodaChihiro UkaiTakuma HigoKohei OkaYasushi Sekine
Published in: Chemical communications (Cambridge, England) (2024)
Lean-burn engines are gaining attention for their lower CO 2 emissions, higher thermal efficiency, and improved fuel economy compared to traditional combustion engines. However, they present some difficulty for reducing nitrogen oxides (NO x ) because of residual oxygen. To address this difficulty, NO x storage reduction (NSR) system, which combines noble metals and NO x adsorbents, is developed as a viable approach. But it requires cyclic operation, which adversely affects fuel efficiency. A novel approach proposed in this work is electric field-assisted lean NO x reduction, which applies an electric field to the NSR catalyst during lean conditions. This innovation uses surplus vehicle electricity for exhaust purification, enhances hydrogen transfer, and improves NO x reduction, even at low temperatures. Tests with a 3 wt% Pt-16 wt% BaO/CeO 2 catalyst demonstrate markedly higher NO x conversion to N 2 (13.1% vs. 2.9% without an electric field). This process is effective with extended electric field exposure, doubling the conversion rate. Electric field-assisted lean NO x reduction, by improving NSR technology, can enhance NO x conversion efficiency, reduce emissions, and optimize fuel efficiency in lean-burn engines.
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