Mechanism and quantitative assessment of saturation transfer for water-based detection of the aliphatic protons in carbohydrate polymers.
Yang ZhouPeter C M van ZijlJiadi XuNirbhay N YadavPublished in: Magnetic resonance in medicine (2020)
The predominant mechanism underlying aliphatic signals in Z-spectra of mobile carbohydrate polymers is intramolecular relayed NOE transfer followed by proton exchange.