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Luminescent Supramolecular Ionic Frameworks based on Organic Fluorescent Polycations and Polyanionic Phosphorescent Metal Clusters.

Ilya V KashnikBinying YangSpartak S YarovoiTaisiya S SukhikhMarie CordierGrégory TaupierKonstantin A BrylevPierre-Antoine BouitYann Molard
Published in: Chemistry (Weinheim an der Bergstrasse, Germany) (2024)
Emissive ionic supramolecular frameworks are designed by associating tetraphenylethylene-based tetra-cationic units and di-anionic molybdenum or tetra-anionic rhenium octahedral clusters. Obtained structures were characterized by single-crystal X-ray diffraction. The emission properties of the hybrids were investigated as dry powders or in various solvents by one photon and two photon absorption leading to a O 2 concentration dependent luminescence color for the Mo based hybrid.
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