Modulation of Polarization in Sliding Ferroelectrics by Introducing Intrinsic Electric Fields.

The emergence of sliding ferroelectricity facilitates low-barrier ferroelectrics in two-dimensional materials, while limited electric polarizations impede practical applications. Herein, we propose an effective strategy to enlarge the polarization by introducing an intrinsic electric field, exemplified by Janus transition metal dichalcogenides (TMDs) with the first-principle calculations. The intrinsic electric field is introduced and regulated by leveraging the electronegativity differences among chalcogens. An improved polarization is achieved in the Janus TeMoS bilayer with a polarization of 1.18 pC/m, a 65% enhancement compared to normal TMD bilayers. Through differential charge density analysis, the inner mechanism is attributed to the effects of intrinsic electric fields on charge redistribution. Furthermore, the feasibility of polarization reversal is determined by evaluating switching barriers and the responses under an electric field. The provided proposal is applicable and available for broader systems and will pave the way for the development of novel electronic devices.