Enhanced oxygen storage capacity of cation-ordered cerium-zirconium oxide induced by titanium substitution.

Yoshihiro Goto Akira MorikawaMasaoki IwasakiMasahide MiuraToshitaka Tanabe

Published in: Chemical communications (Cambridge, England) (2018)

Herein, we report on the synthesis of Ce0.5Zr0.5-xTixO2 oxygen storage materials prepared via a solution combustion method. Ce0.5Zr0.4Ti0.1O2 showed an outstanding oxygen storage capacity (1310 μmol-O per g) at 200 °C compared to conventional κ-Ce2Zr2O8 (650 μmol-O per g) due to its cation ordering and the formation of weakly bound oxygen atoms induced by Ti substitution.

Keyphrases

pet imaging
ionic liquid
energy transfer
particulate matter
risk assessment
air pollution
quantum dots
municipal solid waste
transition metal