Dual stimuli-responsive phosphorescence of a Pb(II) coordination polymer to acidic vapors and thermal treatment.
Sujitra TunsrichonKittipong ChainokVinich PromarakSuangsiri ArunlimsawatSujittra YoungmeJaursup BoonmakPublished in: Dalton transactions (Cambridge, England : 2003) (2023)
We present a new intensely phosphorescent Pb(II) coordination polymer (1) containing a heteroatomic ligand. It has a quantum yield of 21.62% and a lifetime of 25.46 μs. The naked-eye solid-state photoluminescence of 1 significantly changes in response to acidic vapors and thermal treatment, indicating the coexistence of acidochromic and thermochromic luminescence.