Design and synthesis of high performance magnetically separable exfoliated g-C 3 N 4 /γ-Fe 2 O 3 /ZnO yolk-shell nanoparticles: a novel and eco-friendly photocatalyst toward removal of organic pollutants from water.

Herein, a new visible-light active exfoliated g-C 3 N 4 /γ-Fe 2 O 3 /ZnO yolk-shell nanoparticles (NPs) was synthesized as a magnetically separable photocatalyst. For an in-depth understanding of the magnetic photocatalyst's structural, morphological, and optical properties, the products were extensively characterized with FT-IR, XRD, TEM, HRTEM, FESEM, EDS, EDS-mapping, VSM, DRS, EIS, and photocurrent. The photocatalyst was then utilized to degrade Levofloxacin (LEVO) and Indigo Carmine (IC) by visible light at room temperature. The exfoliated g-C 3 N 4 /γ-Fe 2 O 3 /ZnO yolk-shell NPs photocatalyst revealed 80% and 95.6% degradation efficiency for Levofloxacin and Indigo Carmine within 25 and 15 min, respectively. In addition, the optimal factors such as concentration, loading of photocatalyst, and pH were also assessed. Levofloxacin degradation mechanistic studies showed that electrons and holes significantly contribute to the photocatalytic process of photocatalyst degradation. In addition, after 5 times regeneration, exfoliated g-C 3 N 4 /γ-Fe 2 O 3 /ZnO yolk-shell NPs remained as an excellent magnetic photocatalyst for the eco-friendly degradation of Levofloxacin and Indigo Carmine (76% and 90%), respectively. The superior photocatalytic performance of exfoliated g-C 3 N 4 /γ-Fe 2 O 3 /ZnO yolk-shell nanoparticles (NPs) was mostly ascribed to the synergistic advantages of stronger visible light response, larger specific surface area, and the more effective separation and transfer of photogenerated charge carriers. Based on these results, the highly effective magnetic photocatalyst achieved better results than numerous studied catalysts in the literature. The degradation of Levofloxacin and Indigo Carmine under environmentally friendly conditions can be achieved using exfoliated g-C 3 N 4 /γ-Fe 2 O 3 /ZnO yolk-shell NPs (V) as an efficient and green photocatalyst. The magnetic photocatalyst was characterized by spectroscopic and microscopic methods, revealing a spherical shape and particle size of 23 nm. Additionally, the magnetic photocatalyst could be separated from the reaction mixture by a magnet without significantly reducing its catalytic activity.