Dynamic Catalytic Mechanism of the Methanol-to-Hydrocarbons Reaction over Zeolites.

ConspectusThe methanol-to-hydrocarbons (MTH) process has provided a new route to obtaining basic chemicals without relying on an oil resource. Acidity and shape selectivity endow the zeolite with a decisive role in MTH catalysis. However, the inherent reaction characteristics of the MTH reaction over zeolites, such as the complexity of catalytic reaction kinetics, the diversity of catalytic reaction modes, and even the limitations of catalytic and diffusive decoupling, have all confused people with respect to obtaining a comprehensive mechanistic understanding. By examining the zeolite-catalyzed MTH reaction from the perspective of chemical bonding, one would realize that this reaction reflects the dynamic assembly process of C-C bonds from C1 components to multicarbon products. The key to understanding the MTH reaction lies in the mechanism by which C-C bonds are formed and rearranged in the confined microenvironment of the channel or cage structures of zeolite catalysts to achieve shape-selective production.The applications of advanced in situ spectroscopy as well as computational chemistry provide tremendous opportunities for capturing and identifying the details of the structure and properties of reactants, intermediates, and products in the confined reaction space of zeolite channels or cages, observing the real-time dynamic evolution of the catalytic surface, and modeling the elementary reaction steps at the molecular and atomic levels.In this Account, the dynamic catalytic mechanism of the zeolite-catalyzed MTH reaction will be outlined based on decades of continuous research and in-depth understanding. The combination of advanced in situ spectroscopy and theoretical methods allowed us to observe and simulate the formation, growth, and aging process on the working catalyst surface and thus map the dynamical evolution of active sites from a Brønsted acid site (BAS) to an organic-inorganic hybrid supramolecule (OIHS) in the MTH reaction. Moreover, the ever-evolving dynamic succession of the OIHS from surface methoxy species (SMS) to active ion-pair complexes (AIPC) to inert complexes (IC) guided the dynamic autocatalytic process from initiation to sustaining and then to termination, resulting in a complex interlaced hypercycle reaction network. The concept of dynamic catalysis will provide deep insight into the complex catalytic mechanisms as well as the structure-activity relationships in MTH chemistry. More importantly, we are now getting closer to the nature of zeolite catalysis beyond the traditional view of BAS catalysis.