Electrospinning Polyvinyl Alcohol Reinforced with Chitin: The Effect of the Degree of Acetylation.

Nanocomposites made via electrospinning were constructed of polyvinyl alcohol (PVA) and chitin. Chitin was extracted from a natural source ( Fomes fomentarius ), which allowed for precise control of the chemical properties of the resulting material. Chitin was chosen as a filler due to its low cost and widespread availability. Increasing the degree of acetylation of the chitin increased the Young's Modulus of the resulting fiber mats but only at relatively high levels. While composites at lower acetylation levels were stable, no increase in the Young's Modulus was observed, presumably due to decreased intermolecular bonding among fibers. The results suggest that precise control of the degree of acetylation of chitin, more than the loading amount and dispersibility, significantly impacts composite formation.