Recent Advances in Carbazole-Based Self-Assembled Monolayer for Solution-Processed Optoelectronic Devices.

Self-assembled molecules (SAMs) have shown great potential in the application of optoelectronic devices due to their unique molecular properties. Recently, emerging phosphonic acid-based SAMs, 2-(9Hcarbazol-9-yl)ethyl]phosphonic acid (2PACz), have successfully applied in perovskite solar cells (PSCs), organic solar cells (OSCs) and perovskite light emitting diodes (PeLEDs). More importantly, impressive results based on 2PACz SAMs are reported recently in succession. Therefore, it is essential to provide an insightful summary to promote it further development. In this review, the molecule design strategies about 2PACz are first concluded. Subsequently, this work systematically reviews the recent advances of 2PACz and its derivatives for single junction PSCs, tandem PSCs, OSCs and PeLEDs. Finally, this work concludes and discusses future challenges for 2PACz and its derivatives to further develop in optoelectronic devices.