Anion-assisted amidinium exchange and metathesis.

Oleg Borodin Yevhenii ShchukinJonas SchmidMax von Delius

Published in: Chemical communications (Cambridge, England) (2022)

Dynamic covalent chemistry has become an invaluable tool for the design and preparation of adaptable yet robust molecular systems. Herein we explore the scope of a largely overlooked dynamic covalent reaction - amidinium exchange - and report on conditions that allow formal amidinium metathesis reactions.

Keyphrases

ionic liquid
molecularly imprinted
drug discovery
single molecule
high resolution