Late-stage derivatization of a (B,O) 2 -doped perylene.
Omar OuadoudiTanja KaehlerEnes Görkem ÇevikMichael BolteBerthold StögerAlexander V VirovetsHans-Wolfram LernerMatthias WagnerPublished in: Dalton transactions (Cambridge, England : 2003) (2022)
Regioselective di- and tetrabrominations of the (B,O) 2 -perylene 1 afford derivatives 2-4. Despite their poor solubility, 2 and 4 could be used in Stille-type coupling reactions to introduce two CCMe (5) or four CC( p -C 6 H 4 t Bu) substituents (6), respectively. The alkynylated derivatives show blue-green photoluminescence with appreciable quantum efficiencies.
Keyphrases
- quantum dots
- energy transfer
- structure activity relationship
- ms ms
- molecular dynamics
- light emitting
- liquid chromatography tandem mass spectrometry
- high performance liquid chromatography
- liquid chromatography
- gas chromatography mass spectrometry
- simultaneous determination
- highly efficient
- escherichia coli
- mass spectrometry
- solid phase extraction
- cystic fibrosis