Design of a Super-Liquid Crystal-Phobic Coating for Immobilizing Liquid Crystal μ-Droplets─Without Affecting Their Sensitivity.

The aqueous interface of nematic liquid crystal (LC) that undergoes a triggered change in ordering transition of mesogens under an appropriate stimulus has emerged as an important tool for various relevant applications. Further, the confinement of LC into a micrometer dimension appeared to be a facile approach for improving their relevant features and performance. However, the optical characterization of ordering transition in a single micrometer-sized, bare, and free-floating LC droplet in the aqueous phase is an extremely challenging task due to unavoidable Brownian motion, which limits its scope for practical applications. Here, we exploited the 1,4-conjugate addition reaction to report a multilayer coating of a reactive nanocomplex that displayed an extreme repellence to beaded LC droplets with tailored adhesive force through the association of adequate orthogonal chemical modifications with glucamine and selected alkyl acrylates. Further, a spatially selective underwater adhesive super-LC-phobic pattern on a hydrophobic background was developed for immobilizing bare and micrometer-sized LC droplets from their aqueous dispersion without having any arbitrary spillage of the aqueous medium. The settled micrometer-sized LC droplets remained efficient for the triggered change in ordering transition from bipolar (having boojum defects at poles) to radial (with a single defect in the center) configuration. Eventually, a simple and fundamentally distinct chemical strategy of immobilizing a soft and functional material by associating bio-inspired wettability allowed to demonstrate the repetitive triggered LC ordering transition in a single and bare LC droplet.