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Ni-Co hexacyanoferrate hollow nanoprism with CN vacancy for electrocatalytic benzyl alcohol oxidation.

Chenghang LvLiang ChenJingjing BaiHongyu RuoYanlong PanShoudong XuJiaqi ChenDing ZhangChunli Guo
Published in: Chemical communications (Cambridge, England) (2024)
An innovative method to improve the oxidation efficiency of benzyl alcohol utilizes Ni-Co hexacyanoferrate hollow nanoprisms. Synthesized via a gentle self-sacrificial template method, this catalyst exhibits substantial catalytic activity and selectivity towards benzyl alcohol oxidation, facilitated by the strategic incorporation of Co to modulate CN vacancy density. Impressively, it achieves a current density of 10 mA cm -2 at 1.33 V and a remarkable 98% efficiency in benzyl alcohol conversion at 1.4 V.
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