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Tuning the Channel Size and Structure Flexibility of Metal-Organic Frameworks for the Selective Adsorption of Noble Gases.

Liang YuShunshun XiongYuhan LinLiangying LiJunjie PengWei LiuXiaoxi HuangHao WangJing Li
Published in: Inorganic chemistry (2019)
Two ultramicroporous metal-organic frameworks, Zn(ox)0.5(trz) and Zn(ox)0.5(atrz) (ox = oxalate, trz = triazolate, and atrz = 3-aminotriazolate), have been synthesized and tested for the adsorptive separation of Xe and Kr. We demonstrate that the Xe/Kr adsorption selectivity relates to the pore size as well as the structure flexibility of the adsorbents.
Keyphrases
  • metal organic framework
  • aqueous solution
  • heavy metals
  • low density lipoprotein
  • liquid chromatography
  • risk assessment