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Stability Efficiencies of POSS and Microalgae Extracts on the Durability of Ethylene-Propylene-Diene Monomer Based Hybrids.

Traian ZaharescuCarmen Mateescu
Published in: Polymers (2022)
The EPDM (ethylene-propylene-diene monomer) hybrids with improved thermal and radiation strengths containing 1 and 5 phr of polyhedral oligomeric silsesquioxane (vinyl-POSS, Ov-POSS) and/or 2 phr of microalgae ( Chlorella vulgaris ( CV ) and Spirulina platensis ( SP )) powders were investigated in respect to their thermal stability after γ-irradiation. The material durability under accelerated degradation was qualified by chemiluminescence and gelation, which prove the contribution of inorganic filler and microalgae extracts on the increase of hybrid thermal stability, as well as the interaction between added components (POSS and CV or SP ). The activation energies and the durabilities under accelerated degradation were calculated, indicating their suitable usage as appropriate materials in various applications. The reported results indicate the improvement effect of both microalgal powders on the oxidation strength, but the contribution of Spirulina platensis grabs attention on its efficient effects upon the prevention of degradation under accelerated aging conditions. The thermal performances of the tested EPDM based hybrids are remarkably ameliorated, if the certain formulation includes Ov-POSS (5 phr) and Spirulina platensis (2 phr), certifying its suitability for the pertinent applications.
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