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Highly luminescent olefin-linked covalent organic frameworks.

Xinyu WuLina ZongNing Huang
Published in: Chemical communications (Cambridge, England) (2023)
A new olefin-linked covalent organic framework (COF) was developed using 1,3,5-triformylbenzene (TFB) and tetraethyl p -xylylenediphosphonate (TEXDP) as building blocks through a Horner-Wadsworth-Emmons reaction. By combination of the aromatic columnar ordering and high conjugation, the resulting TFB-TEXDP-COF exhibits a fluorescence quantum yield of up to 41%, which constitutes the new record value among COFs.
Keyphrases
  • energy transfer
  • water soluble
  • quantum dots
  • single molecule
  • sensitive detection
  • amino acid