Self-Assembled 3D Hierarchical Copper Hydroxyphosphate Modified by the Oxidation of Copper Foil as a Recyclable, Wide Wavelength Photocatalyst.

In this work, three-dimensional flower-like and petal-like copper hydroxyphosphate Cu5(OH)4(PO4)2 (CHP) based on the self-assembly of numerous nanosheets has been successfully fabricated on a copper foil by a mild one-pot wet-chemical method without ligand assistance. This research contributes to the development of the method to change the morphology of the CHP active material by varying the degree of substrate oxidation. The two different CHP architectures were used to photocatalytically degrade rhodamine 6G (Rh 6G) under solar light, which can absorb wide-range light wavelength from the UV to the near-infrared region. They all exhibit high photocatalytic activity and good durability, which are potential candidates for high performance and recyclable wide wavelength photocatalysis.