A hexameric [MnNa6] wheel based on [MnO]7+ sub-units.

Maria ManoliRoss InglisStergios PiligkosLan YanhuaWolfgang WernsdorferEuan K BrechinAnastasios J Tasiopoulos

Published in: Chemical communications (Cambridge, England) (2018)

A novel hexameric [MnNa6] wheel-like aggregate consisting of [MnO] triangles is reported. It is the second highest nuclearity oxime-based Mn cluster, the largest member of the recently-developed family of molecular oligomers based on [MnO] triangles, and the only one with a wheel-like metal topology.

Keyphrases

metal organic framework
ionic liquid
transition metal