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Directed Autonomous Motion and Chiral Separation of Self-Propelled Janus Particles in Convection Roll Arrays.

Poulami BagShubhadip NayakTanwi DebnathPulak Kumar Ghosh
Published in: The journal of physical chemistry letters (2022)
Self-propelled Janus particles exhibit autonomous motion thanks to engines of their own. However, due to the randomly changing direction of such motion they are of little use for emerging nanotechnological and biomedical applications. Here, we numerically show that the motion of chiral active Janus particles can be directed, subjecting them to a linear array of convection rolls. The rectification power of self-propulsion motion here can be made to be more than 60%, which is much larger than earlier reports. We show that rectification of a chiral Janus particle's motion leads to conspicuous segregation of dextrogyre and levogyre active particles from a racemic binary mixture. Further, we demonstrate how efficiently the rectification effect can be exploited to separate dextrogyre and levogyre particles when their intrinsic torques are distributed with Gaussian statistics.
Keyphrases
  • high speed
  • ionic liquid
  • capillary electrophoresis
  • high resolution
  • high throughput
  • mass spectrometry
  • liquid chromatography