Substrate-Assisted Atomic Dispersion of Cobalt for Alkaline Water Electrolysis.

Atomically dispersed single-atom catalysts have recently attracted broad research interest due to their high atom efficiency and unique catalytic performance. In this study, atomic dispersion of cobalt is achieved using a chemical bath deposition method on a highly stable alkali titanate film (Ti/KTiO). These films were characterized using a variety of techniques, with atomic dispersion confirmed via grazing incidence X-ray absorption spectroscopy and ab initio modeling of single-atom systems. This modeling indicated that the alkali ion incorporated into the film facilitates atomic dispersion. Experimentally, the Ti/KTiO-supported Co(OH) 2 catalysts exhibited remarkable electrochemical performance, with an overpotential of 163 mV to achieve a current density of 10 mA cm -2 with a catalyst loading of ∼0.1 mg cm -2 and high stability. These results show the potential of Ti/KTiO/Co(OH) 2 catalysts for atomically efficient hydrogen production.