Emission Characteristics of Aerosols Generated during the Micro-Nano Bubble Aeration Process in Wastewater.

Micro-nano bubble (MNB) aeration is an emerging technology that considerably enhances the aeration efficiency of wastewater. This study evaluates, for the first time, aerosolization at the water-air interface during MNB aeration. Our results show that the concentration of culturable mixed microorganisms (i.e., bacteria, fungi, and intestinal bacteria) in the in situ MNB generation (MNBs-G) phase is 2170 CFU/m 3 , 1.38 and 1.58-fold higher than those in medium-bubble aeration (MBA; 1568 CFU/m 3 ) and small-bubble aeration (SBA; 1376 CFU/m 3 ) aerosols, respectively. Conversely, the concentration of culturable mixed microorganisms in the MNB persistent dissolved oxygen (MNBs-O) phase is only 914 CFU/m 3 . Microbiological analysis shows a lower abundance of bacterial pathogens in MNBs-G (34.12%) and MNBs-O (34.02%) phases than in MBA (39.63%) and SBA (38.87%) aerosols. Acinetobacter is prevalent in MNBs-G (14.76%) and MNBs-O (8.22%) aerosols, whereas Bacillus and Arcobacter are prevalent in MBA (23.96%) and SBA (6.92%) aerosols, respectively. The total concentrations of chemicals [i.e., total organic carbon, water-soluble ions, and metal(loid)s] in aerosols formed via MNB aeration (205.98-373.74 μg/m 3 ) are lower than those in MBA and SBA (398.69-594.92 μg/m 3 ). Compared to MBA and SBA, the MNBs-G phase exhibits higher emissions of 12 elements in aerosols (i.e., NO 3 - , NO 2 - , Ca 2+ , Na + , K + , Mg 2+ , Zn, Cd, Fe, Mn, As, and Cr), whereas the MNBs-O phase generally shows lower emissions. These findings highlight the potential of optimized MNB aeration technology in considerably mitigating aerosol emissions and thereby advancing environmental sustainability in wastewater treatment.