Pineapple-Leaf-Derived, Copper-PAN-Modified Regenerated Cellulose Sheet Used as a Hydrogen Sulfide Indicator.
Surached ThongboonThanaphat ChukeawChalida NiamnuySupacharee RoddechaPaweena PrapainainarMetta ChareonpanichPassakorn KingwascharapongKajornsak FaungnawakijGünther RupprechterAnusorn SeubsaiPublished in: ACS omega (2023)
Regenerated cellulose (RC) produced from waste pineapple leaves was used to develop a colorimetric sensor as a Cu-PAN sheet (RCS). Microcrystalline cellulose derived from dried pineapple leaves was combined with Cu-PAN, dissolved in NaOH and urea, and made into an RC sheet using Na 2 SO 4 as a coagulant. The RCS was used as an H 2 S indicator at various H 2 S concentrations (0-50 ppm) and temperatures (5-25 °C). The RCS color changed from purple to New York pink when exposed to H 2 S. A colorimeter method was used to develop prediction curves with values of R 2 > 0.95 for H 2 S concentrations at 5-25 °C. The physicochemical properties of fresh and spent RCS were characterized using various techniques (Fourier transform infrared spectroscopy, X-ray diffraction, scanning electron microscopy/energy-dispersive X-ray spectroscopy, and thermogravimetric analysis). In addition, when stored at 5 and 25 °C for 90 days, the RCS had outstanding stability. The developed RCS could be applied to food packaging as an intelligent indicator of meat spoilage.
Keyphrases
- electron microscopy
- aqueous solution
- ionic liquid
- high resolution
- gold nanoparticles
- magnetic resonance
- heavy metals
- room temperature
- mass spectrometry
- single molecule
- nitric oxide
- risk assessment
- computed tomography
- quantum dots
- sensitive detection
- oxide nanoparticles
- metal organic framework
- hydrogen peroxide
- tandem mass spectrometry
- fluorescent probe