Influence of Anchoring Groups on the Charge Transfer and Performance of p-Si/TiO2/Cobaloxime Hybrid Photocathodes for Photoelectrochemical H2 Production.

Although hybrid photocathodes built by immobilizing molecular catalysts to the surface of semiconductors through chemical linkages have been reported in recent years, systematic and comparative studies remain scarce about the impact of various anchoring groups on the performance, stability, and charge-transfer kinetics of molecular catalyst-decorated hybrid photocathodes for photoelectrochemical (PEC) H2 production. In this study, the molecular cobaloxime catalysts, CoPy-4-X (Py = pyridine, X = PO3H2, COOH, and CONH(OH)), bearing different anchoring groups were synthesized and covalently immobilized to the surface of the porous TiO2 layer coated on a p-Si plate or a fluorine-doped tin oxide glass. The influence of the anchoring groups on the performance of p-Si/TiO2/CoPy-4-X photocathodes was comparatively studied for PEC H2 evolution. Among the tested hybrid photocathodes, the one with a hydroxamate as an anchoring group displayed higher activity and lower charge-transfer resistance than that observed for the electrode with a carboxylate or a phosphonate as the anchoring group. Notably, the catalytic current of p-Si/TiO2/CoPy-4-CONH(OH) was attenuated only by 2.9% in the controlled potential photoelectrolysis tests in borate buffer solution at pH 9 at 0 V versus a reversible hydrogen electrode over 6 h. Moreover, the influence of anchoring groups on the interfacial electron transfer from the TiO2 layer to the immobilized cobaloxime catalyst and electron-hole recombination was studied by transient absorption spectroscopy. These results revealed that the hydroxamate as an anchoring group is superior to the carboxylate and phosphonate groups for speeding up the interfacial electron transfer and firmly immobilizing the molecular catalysts to the metal oxide semiconductors to build efficient and stable hybrid photoelectrodes.