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Dynamical scaling in the Ohmic spin-boson model studied by extended hierarchical equations of motion.

Qianlong WangZhihao GongChenru DuanZhoufei TangJianlan Wu
Published in: The Journal of chemical physics (2019)
Through a decomposition of the bath correlation function, the hierarchical equations of motion are extended to the Ohmic spin-boson model at zero temperature. For two typical cutoff functions of the bath spectral density, the rate kernel of spin dynamics is numerically extracted by a time-convolution equation of the average magnetic moment. A characteristic time is defined accordingly as the inverse of the zeroth-order moment of the rate kernel. For a given Kondo parameter in the incoherent regime, the time evolution of average magnetic moments gradually collapses onto a master curve after rescaling the time variable with the characteristic time. The rescaled spin dynamics is nearly independent of the cutoff frequency and the form of cutoff functions. For a given cutoff frequency, the characteristic time with the change of the Kondo parameter is fitted excellently as a function of the renormalized tunneling amplitude. Despite a significant difference in definition, our result is in good agreement with the characteristic time of the noninteracting blip approximation.
Keyphrases
  • density functional theory
  • room temperature
  • single molecule
  • transition metal
  • molecular dynamics
  • molecularly imprinted
  • high speed
  • magnetic resonance
  • diffusion weighted imaging