Iron-Catalyzed Intramolecular Aminations of C(sp3 )-H Bonds in Alkylaryl Azides.

Isabel T AltClaudia GuttroffBernd Plietker

Published in: Angewandte Chemie (International ed. in English) (2017)

The nucleophilic iron complex Bu4 N[Fe(CO)3 (NO)] (TBA[Fe]) catalyzes the direct intramolecular amination of unactivated C(sp3 )-H bonds in alkylaryl azides, which results in the formation of substituted indoline and tetrahydroquinoline derivatives.

Keyphrases

iron deficiency
energy transfer
metal organic framework
molecular docking
room temperature
aqueous solution
visible light
transition metal
ionic liquid