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High Energy Storage Performance in La-Doped AgNbO 3 Ceramics via Tape Casting.

Mingyuan ZhaoJing WangHao YuanZehan ZhengLei Zhao
Published in: ACS applied materials & interfaces (2022)
AgNbO 3 -based Pb-free antiferroelectric (AFE) ceramics have attracted increasing interest owing to their excellent potential in energy storage applications. Herein, a high recoverable energy storage density ( W rec ) of 7.62 J/cm 3 is realized in La-doped AgNbO 3 ceramics prepared via tape casting. The high W rec is attributed to high breakdown strength E b of 380 kV/cm induced by dense microstructure as well as fine grain size and enhanced AFE stability stemming from M 2 phase and reduced tolerance factor t . The high W rec exceeding 6 J/cm 3 was maintained in a wide temperature range of 20-150 °C and exhibited frequency stability with less than 8% variation in a range of 1-200 Hz. The discharge energy density W d exhibited temperature stability at 30-110 °C with less than 9% variation. Our research provides a good method for producing AgNbO 3 -based ceramics having high energy storage performances.
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