Removal of methylene blue dye by solvothermally reduced graphene oxide: a metal-free adsorption and photodegradation method.

In this work, reduced graphene oxide (rGO) was fabricated at different reduction temperatures via an environmentally friendly solvothermal approach. The rGO formed at 160 °C clearly showed the partial restoration of the sp 2 hybridization brought about by the elimination of oxygenated functionalities from the surface. Owing to the augmented surface area and the band gap reduction, rGO-160 exhibited the best adsorption (29.26%) and photocatalytic activity (32.68%) towards the removal of MB dye. The effects of catalyst loading, initial concentration of dye, light intensity, and initial pH of solution were evaluated. It was demonstrated that rGO-160 could achieve a higher adsorptive removal (87.39%) and photocatalytic degradation (98.57%) of MB dye when 60 mg of catalyst, 50 ppm of dye at pH 11, and 60 W m -2 of UV-C light source were used. The MB photodegradation activity of rGO-160 displayed no obvious decrease after five successive cycles. This study provides a potential metal-free adsorbent-cum-photocatalyst for the decontamination of dyes from wastewater.